I've been trying to make molds out of 3D-printed UV resin masters lately, but the platinum-cure liquid silicone has been failing to cure. I've tried curing it at different temperatures and it still doesn't work.
What material are your 3D-printed molds made of? Is the liquid silicone you're using cured in other situations, such as in disposable plastic cups? I recommend either baking the 3D-printed UV resin master at 60°C to evaporate potential solvents, or spraying the 3D-printed part with clear acrylic paint as a protective coating.